Don't panic, but don't waste any time. This is a situation where speed is definitely crucial! The faster you can get to the urine, the more of it you can get out of the mattress and the less lingering smell you'll have to deal with. This is the perfect application for a wet-dry vac, if you happen to have one. But if you don't, just blot up as much of the wetness as you can. This is a really important part of the process so don't stop with the surface wetness - put pressure on the mattress and try to extract as much of the urine from the inside as possible.
When the mattress is as dry as you can get it, focus on eliminating the lingering odor. There are lots of commercial cat odor eliminators available and one of them is probably your best and safest bet. But if you don't happen to have any of those products at hand, try one of the alternatives below.
Option 1: Soak the urine stain with white vinegar, either straight from the bottle or mixed with water. Let the vinegar sit for a few minutes, then blot as much of it as you can from the mattress. Now scrub the area with dish washing liquid, wipe down with plain water, then sprinkle the area liberally with baking soda and rub it into the fabric. When the baking soda has dried, vacuum the area. This method tends to leave the mattress smelling like vinegar for a while, but it beats the alternative.
Option 2: Make a paste of baking soda and hydrogen peroxide. Work the mixture into the fabric with a brush and let dry, then vacuum up any remaining residue. If the urine smell remains after the mattress is dry, repeat the process. It can take two or three treatments to completely eliminate the smell.
Option 3: Scrub down the area with shampoo or dish washing liquid, then soak the area with rubbing alcohol and let it dry. If the smell remains after the mattress is dry, repeat the process.
If the urine has already dried into the mattress getting rid of the odor will be more difficult. Again, a commercial product specifically made to get rid of cat urine odor will probably be the most effective, but the methods above are definitely worth a shot. Doing the scrubbing outdoors and letting the mattress dry in the sun can help.
It pays to be thorough, because as long as the cat can smell urine in the mattress, she will probably continue to urinate on it. If you have a persistent mattress pee-er, think about scheduling a trip to the vet. This behavior can be a sign of illness such as a urinary tract infection. Cats who are feeling stress may also exhibit this behavior.
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